Maybe do something like what Alan said, but use the LM3916 as the led driver?
Basically opamp set up with vactrol to control gain and the LM3916 controlling the led in the vactrol. To control the LM3916, have the pot on the volume pedal set up as a voltage divider tied to a power source and the control pin of the LM3916. Then you could have a bypass switch for the pot to bring it to max gain?
Makes sense in my mind, don't know if it makes sense here. I'll draw up a basic diagram for what I mean later.
All that said, something like an Arduino is the route I'd go.