madbeanpedals::forum

Projects => General Questions => Topic started by: Vallhagen on July 31, 2013, 07:00:12 PM

Title: Etching enclosures with FeCl3, a few questions
Post by: Vallhagen on July 31, 2013, 07:00:12 PM
Hi folks.

I have done a few (two, to be specific) fairly successful etches on aluminum enclosures. The latest one here: http://www.madbeanpedals.com/forum/index.php?topic=10407.0 (http://www.madbeanpedals.com/forum/index.php?topic=10407.0). More often than twice though, i have failed in my tries to etch them.

My problem has been that the etches dont go enough deep. I guess it depends on the etchant i have used so far, NaOH, commonly known as "Kaustiksoda (Swedish Word. Caustic Soda in English?)". It works, but the effect is weak. I've had enclosures in warm etching baths for 20 minutes, and the patterns goes viewable, but are barely so Deep i can sense them with fingertips.

Anyway, it's time for upgrade and more trial and error! So i just bought me some 125g of FeCl3 (which i guess is what most of you guys use for etching?). The bottle texttag says that it shall dissolve in 0.25-0.5 litres of water to make a good enough solution.

My questions:
How much is needed to prepare for one enclosure? Or do you prepare all of it and save in a bigger bottle?

is the etchant reusable after one enclosure? if so, i'd appreciate some kind of rule by thumb (as in "say 4 boxes need 3dl of etchant...")

How much time is needed to etch a box? I know it depends on font/pattern width etc, but ... Another rule by thumb? If i remember correct, Slade (at DIYSTB) recommended 4-8 minutes in his tutorial. Sounds sane?

Cheers
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: pryde on July 31, 2013, 07:20:06 PM
I don't re-use my FC after an aluminum etch but I also don't use very much of it per-etch either.

Also, I don't dilute it-just take it straight up  8)

What I do is put a puddle of FC about the size of the box on a flat plastic plate. I then tape toothpicks to each corner of the enclosure where they stick up about 2-3mm. When you lay the enclosure face-down in the etchant puddle it will stand-off a bit because of the toothpicks BUT etchant should still be contacting the surface of the faceplate. Then move it around gently to agitate the solution under the box.

Time depends on how much area you are etching, if it is primarily just text and lines then 6-8 minutes should be plenty. If you are etching away large areas then up to 15 minutes may be needed (in my experience) but then you risk over-etching the small text areas, etc.

ASLO: Have a plate of water right next to the etchant plate if the box starts overheating then give it a dip!
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: rullywowr on July 31, 2013, 07:34:46 PM
You may want to try using a little heat under the etching tray to accelerate the process.  You could have a slightly larger pan with hot water that the etching container "floats" in.

While FeCl3 works, I would suggest you try Hydrogen Peroxide (H2O2) and Muriatic Acid (H2sO4).  You can get H2O2 at any drugstore and the Muriatic Acid is usually sold in Hardware Stores for cleaning concrete or even pool stores.  A mixture of 1 part acid to 2 parts H2O2 usually works good for me.  Again, a little heat in the form of a hot water bath under the etching container works well here to speed things up.

The benefits of H2O2 and H2So4 are pretty good:
- Inexpensive and easy to find materials
- You can actually see through the mixture while it is etching to know when its time to stope
- A little less dangerous than used FeCl3 and easier to dispose of.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Vallhagen on July 31, 2013, 08:03:58 PM
I read your hints guys. Thanx.

When you talk about "hot", how hot is that in terms of degrees? The bottle recommends 20-40 Celsius.

... and yea, maybe i will run on to other Chemistry (H2O2 + H2SO4) later on, now i go with FeCL for the first time though:)

Cheers!
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: pryde on July 31, 2013, 11:34:04 PM
I have done all my etches at room temperature (~70-80F) with FC without any issues. Should be fine with some occasional agitation during the etch
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: TwistdDeth on August 03, 2013, 11:11:07 PM
I have been using Muriatic Acid and peroxide in a small bowl only applying acid to the areas favored to be etched to reduce over etching small text. This, to me, adds a bit of control to the etch process. See my R2G2 build (http://www.madbeanpedals.com/forum/index.php?topic=10476.0) for an example of detail.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: timbo_93631 on August 06, 2013, 03:36:49 AM
Quote from: TwistdDeth on August 03, 2013, 11:11:07 PM
I have been using Muriatic Acid and peroxide in a small bowl only applying acid to the areas favored to be etched to reduce over etching small text. This, to me, adds a bit of control to the etch process. See my R2G2 build (http://www.madbeanpedals.com/forum/index.php?topic=10476.0) for an example of detail.

I use the same, though it has been used to dissolve copper from PCB's first so it became cupric chloride.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: jimilee on August 06, 2013, 04:01:59 AM
This while process is a bit scary to me, that's why I use enviro instead. It is intriguing though.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Vallhagen on August 06, 2013, 05:56:14 PM
Quote from: TwistdDeth on August 03, 2013, 11:11:07 PM
I have been using Muriatic Acid and peroxide in a small bowl only applying acid to the areas favored to be etched to reduce over etching small text. This, to me, adds a bit of control to the etch process. See my R2G2 build (http://www.madbeanpedals.com/forum/index.php?topic=10476.0) for an example of detail.

Yea, i have noticed that darth vader friendly etch earlier :). Great job.

I gotta ask though, how do you mean by "only applying on ... [specific] areas"? I mean, the box is a flat Surface, its hard to just dip a corner etc... Or do you mean that you cover the areas that you dont want to etch with tape or something?  Sorry if the question sounds stupid, but i dont really get it :)

***

And thanx all for great hints and replies. I had plans to do some etching right when i started this thread, then something came inbetween... But ill be back with result, for sure:)

Cheers
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Gledison on August 06, 2013, 06:55:23 PM
Hey Vallhagen, im not an etch expert, but a chemist :P
I think u are already doing the right things. In order to get deeper etching, try to "wash" the parts you are etching with the Ferric chloride. you need to keep "fresh" oxidizing agent in contact with the desired etching parts. IF you are etching just little parts, you can re-use it several times without problem>of course after around 2o times, might not work anymore and you need a fresh one!
ive seen somewhere a guy brushing the etching area with a little piece of a sponge. PLEASE USE GLOVES!!!
it helps to remove the oxidized parts and bring more ferric chloride in contact with the aluminium...
good luck!
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Clayford on August 11, 2013, 12:57:43 AM
I got a rather nice sized bottle of Ferric Chloride from Amazon and am looking at this (http://dl.dropboxusercontent.com/u/3565959/%5BTutorial%5D%20Making%20a%20Multicolor%20Etching.pdf) guide on doing an etch. Seems to be rather comprehensive and his etches are always amazing.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Clayford on August 11, 2013, 02:52:10 AM
double post deleted.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: rosettastoned on August 11, 2013, 06:52:11 AM
in Chile FeCl3 this is not an expensive product, you can get a 500CC. bottle for 4 dollars and it last a lot. I usually use this method to my builds ( reverse extchin') and just need a sharp knife to do the job.

(http://s18.postimage.org/f8al0tf1l/IMG_0801.jpg)%20(http://postimage.org/)
(http://img411.imageshack.us/img411/332/img4358e.jpg)
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: hammerheadmusicman on August 11, 2013, 02:33:41 PM
^Those reverse Etches are SLICK!

George
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: m-Kresol on October 19, 2014, 09:34:42 AM
Ancient thread revival!
I have some questions about etching enclosures since I seem to fail at it. I get results, but they are way off of what I want and what some of you (Cody and Graham :) ) achieve. I'm supposed to be an expert on a topic like this, but I keep having the same problem, so here it goes:

I always have the etchant eat through my mask at some point. I tried photoresist at first and I thought it was because of the uneven coats you get with the rattle can application I have. So I switched to toner transfer. I tried three different papers, two of them worked fine. The inkjet photo paper was a nightmare as it glued itself to the enclosure at random and was a pain to get off due to melted plastic coatings.
Once I finally had the perfect toner transfer, I etched with NaOH as per grahams tutorial since it is the cheaper chemical to "borrow" from the lab. The result was rather poor having lots of fine details etched away. To be fair, I didn't pay to much attention to it, as I just did it on the side while working. I recently did an etch again with FeCl3 as per Cody's tutorial and it worked well except for the problem that the etchant ate through the mask at some point making the enclosure looking not half as good.

*What am I doing wrong? Is my solution too concentrated? my pH too low/high (I added a little hydrochloric acid to regenerate the FeCl3 solution so it is rather acidic)?
*I guess, so long as the toner transfers completely, I got a good combination of printer and paper, right? or is there a specific toner?
*Am I etching too long? It takes me about 15 - 20 min I guess. I tend to lightly scrub off the rusty looking gunk to see the depth of the etch. Could it be that I remove part of the toner there? How deep are your etches? I tend to think that I etch too long and deeper than necessary.

I appreciate any input you could throw my way. I put quite some time into this, but couldn't get it solved. Trial and error would probably lead to a working procedure, but as the semester started again and my boss is pushing me lately, I don't have the time for that atm.
Thanks for all your wonderful tutorials guys and thanks for any comments!
Cheers,
Felix

P.S.: this is haunting me so badly, that I even dreamt about Cody. In a non-romantical-he's-showing-me-how-to-etch way :D This stuff is starting to wreck my brain
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Gledison on October 19, 2014, 10:52:44 AM
Hey mate, another chemistry expert here but not much on etching, but I think ur etching solution is not the problem as u are getting a nice etch. I think that u should try the easier thing a first. perhaps your masking tape is too porous and the FeCl3 is penetrating  through it! I would choose tapes that have a good adhesion to metal and not paper backing.
pS:Cody 'a tutorial indeed is great!
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: m-Kresol on October 19, 2014, 11:52:44 AM
thanks for your answer. The masking tape is not the issue; it's about the etch mask, so either the toner or the photoresist. The etchant is penetrating through both after some time. the sides of the enclosure are fine.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: selfdestroyer on October 20, 2014, 12:09:40 AM
Quote from: m-Kresol on October 19, 2014, 09:34:42 AM
P.S.: this is haunting me so badly, that I even dreamt about Cody. In a non-romantical-he's-showing-me-how-to-etch way :D This stuff is starting to wreck my brain

LOL, My wife just printed out the paperwork for a restraining order, you know.. just in case. lol

This has been a hard thing for me ever since I place my tutorial up on my blog and I get mixed results from people. I really think there are just so many variables and its really hard to make suggestions that doesn't feel counterintuitive. It sounds like you have tried quite a few things. I can give you a few suggestions and see if they may help and at the very least, point you in the right direction.

Etchant:
I use the Radio Shack Etchant since I can get it locally and I have always had good results.
http://www.radioshack.com/product/index.jsp?productId=2102868 (http://www.radioshack.com/product/index.jsp?productId=2102868)
MSDS Sheet
http://www.radioshack.com/graphics/uc/rsk/Support/MSDS/2761535MSDS.pdf (http://www.radioshack.com/graphics/uc/rsk/Support/MSDS/2761535MSDS.pdf)
As per the MSDS sheet it looks like its only 30-60% chloride so that may be a factor why it doesn't eat through my mask so quickly. So if you are using 100% chloride you may want to dilute it some.

Paper & print density:
I still swear by the HP Premium Presentation paper 120g
http://h30094.www3.hp.com/product.aspx?sku=10250041&mfg_part=CG988A&pagemode=ca (http://h30094.www3.hp.com/product.aspx?sku=10250041&mfg_part=CG988A&pagemode=ca)

Print destiny on HP printers set to the highest setting (5 in my case on the HP LaserJet Pro P1102w)

I really do think I can get finer detail when I agitate the enclosure in the etchant in a up and down motion. I find that  it helps knock off the deposits left from the etchant. I do the same up and down motion in a water bath. I usually put the enclosure in the etchant for 30-40 seconds and then a quick rinse in water. I will repeat this as needed. You can use your finder to gauge how deep the etch is but be careful not to wipe away your mask.

Title: Re: Etching enclosures with FeCl3, a few questions
Post by: m-Kresol on October 20, 2014, 07:01:20 AM
thanks for your advice. I think I might just have overdone it the last times in respect to depth and etching time. My solution is rather concentrated, but 100% is not possible as FeCl3 is a solid ;) I will dilute mine a little further.

Quote from: selfdestroyer on October 20, 2014, 12:09:40 AM
Quote from: m-Kresol on October 19, 2014, 09:34:42 AM
P.S.: this is haunting me so badly, that I even dreamt about Cody. In a non-romantical-he's-showing-me-how-to-etch way :D This stuff is starting to wreck my brain

LOL, My wife just printed out the paperwork for a restraining order, you know.. just in case. lol


No worries, I'm half a continent away and I have too little time for another hobby :D
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Stomptown on October 20, 2014, 07:01:33 AM
Have you tried a different printer or are all of the attempts from the same printer?  I've had a couple bad etches and I've come to the conclusion that all toner is not created equal when it comes to transfers.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: m-Kresol on October 20, 2014, 07:04:11 AM
it was with the same printer. I tried varying the toner density.
I might give the other office printer a shot. Thanks for suggesting
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: TGP39 on October 20, 2014, 07:29:24 AM
Hi everyone. Quick question. Is there any truth that color laser printers won't print quality etching masks?  Should I get a monochrome laser printer? My problem seems to be just getting a quality etching mask onto the damn enclosure. I just purchased some PNP Blue. If that works I'm re-naming it PNP Gold.  ;D
Also want to thank Cody for putting that tutorial together. I was afraid to even try etching prior to watching that. Thank you Cody.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Stomptown on October 20, 2014, 08:01:47 AM
Quote from: TGP39 on October 20, 2014, 07:29:24 AM
Hi everyone. Quick question. Is there any truth that color laser printers won't print quality etching masks?  Should I get a monochrome laser printer? My problem seems to be just getting a quality etching mask onto the damn enclosure. I just purchased some PNP Blue. If that works I'm re-naming it PNP Gold.  ;D
Also want to thank Cody for putting that tutorial together. I was afraid to even try etching prior to watching that. Thank you Cody.


I've used color laser printers at the print shop without issue but I'm not sure about smaller ones.  How long do you spend ironing the transfer to the enclosure?  I Find that insufficient time makes for a bad transfer. I usually go for 15 minutes or so, which I picked up from Pryde's tutorial. Specifically I let the iron sit on the enclosure for 2 minutes. Then I use the tip of the iron to go over the enclosure for two minutes and repeat.

PnP blue is really nice but the technique it quite different compared to using gloss paper. After switching to paper I tried to go back to PnP and had a terrible time with it. Definitely research how to use PnP on enclosures.  At the end if the day etching enclosures is a bit of a black art and it really takes trial and error to make it work. There are so many variables and changing one little thing has huge effects down the line. 

Title: Re: Etching enclosures with FeCl3, a few questions
Post by: selfdestroyer on October 20, 2014, 07:55:45 PM
Quote from: TGP39 on October 20, 2014, 07:29:24 AM
Hi everyone. Quick question. Is there any truth that color laser printers won't print quality etching masks?  Should I get a monochrome laser printer? My problem seems to be just getting a quality etching mask onto the damn enclosure. I just purchased some PNP Blue. If that works I'm re-naming it PNP Gold.  ;D
Also want to thank Cody for putting that tutorial together. I was afraid to even try etching prior to watching that. Thank you Cody.

I have used a color laser from here at work (Konica Minolta) and had good results. Glad you are giving it a go, the more of us etching the more tips and tricks we can all learn from each other to perfect the craft.

Cody
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Justus on October 21, 2014, 01:00:56 AM
The black toner you put into the black slot on a color laser printer is the same black toner you put in a monochrome laser printer.

Just don't let the black toner run out, otherwise the color laser printer will attempt to compensate by using extra c/y/m toner to simulate black.
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: Stomptown on October 21, 2014, 04:45:40 AM
Quote from: Justus on October 21, 2014, 01:00:56 AM
The black toner you put into the black slot on a color laser printer is the same black toner you put in a monochrome laser printer.

Just don't let the black toner run out, otherwise the color laser printer will attempt to compensate by using extra c/y/m toner to simulate black.

Hmm... I wonder if this is the reason I've had issues on occasion. There are two times in particular I can remember where the black toner just didn't look right and the transfer was terrible.  For whatever Reason, C/Y/M compensation never occurred to me!
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: TGP39 on October 21, 2014, 07:14:19 AM
Thank you Jon, Cody and Steve. I'll keep at it. :D
Title: Re: Etching enclosures with FeCl3, a few questions
Post by: m-Kresol on October 21, 2014, 08:40:19 AM
I'll give it another go for my ultrastoner build. I'll try fresh solution and shorter etching times. Thanks guys